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Combustible
A combustible material is something that can burn (i.e., ''combust'') in air. A combustible material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame. The degree of flammability or combustibility in air depends largely upon the volatility of the material - this is related to its composition-specific vapour pressure, which is temperature dependent. The quantity of vapour produced can be enhanced by increasing the surface area of the material forming a mist or dust. Take wood as an example. Finely divided wood dust can undergo explosive combustion and produce a blast wave. A piece of paper (made from wood) catches on fire quite easily. A heavy oak desk is much harder to ignite, even though the wood fibre is the same in all three materials. Common sense (and indeed scientific consensus until the mid-1700s) would seem to suggest that ma ...
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Dust Explosion
A dust explosion is the rapid combustion of fine particles suspended in the air within an enclosed location. Dust explosions can occur where any dispersed powdered combustible material is present in high-enough concentrations in the atmosphere or other oxidizing gaseous medium, such as pure oxygen. In cases when fuel plays the role of a combustible material, the explosion is known as a fuel-air explosion. Dust explosions are a frequent hazard in coal mines, grain elevators, and other industrial environments. They are also commonly used by special effects artists, filmmakers, and pyrotechnicians, given their spectacular appearance and ability to be safely contained under certain carefully controlled conditions. Thermobaric weapons exploit this principle by rapidly saturating an area with an easily combustible material and then igniting it to produce explosive force. These weapons are the most powerful non-nuclear weapons in existence. Terminology If rapid combustion occurs ...
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Flash Point
The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1) The flash point is sometimes confused with the autoignition temperature, the temperature that causes spontaneous ignition. The fire point is the lowest temperature at which the vapors keep burning after the ignition source is removed. It is higher than the flash point, because at the flash point vapor may not be produced fast enough to sustain combustion. Neither flash point nor fire point depends directly on the ignition source temperature, but ignition source temperature is far higher than either the flash or fire point. Fuels The flash point is a descriptive characteristic that is used to distinguish between flammable fuels, such as petrol (also known as gasoline), and combustible fuels, such as diesel. It is also used to characterize th ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is prod ...
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Phlogiston Theory
The phlogiston theory is a superseded scientific theory that postulated the existence of a fire-like element called phlogiston () contained within combustible bodies and released during combustion. The name comes from the Ancient Greek (''burning up''), from (''flame''). The idea was first proposed in 1667 by Johann Joachim Becher and later put together more formally by Georg Ernst Stahl. Phlogiston theory attempted to explain chemical processes such as combustion and rusting, now collectively known as oxidation. It was challenged by the concomitant weight increase, and was abandoned before the end of the 18th century following experiments by Antoine Lavoisier and others. Phlogiston theory led to experiments which ultimately concluded with the discovery of oxygen. Theory Phlogiston theory states that ''phlogisticated'' substances contain phlogiston and that they ''dephlogisticate'' when burned, releasing stored phlogiston which is absorbed by the air. Growing plants then absor ...
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Fire Code
Fire safety is the set of practices intended to reduce the destruction caused by fire. Fire safety measures include those that are intended to prevent the ignition of an uncontrolled fire and those that are used to limit the development and effects of a fire after it starts. Fire safety measures include those that are planned during the construction of a building or implemented in structures that are already standing, and those that are taught to occupants of the building. Threats to fire safety are commonly referred to as fire hazards. A fire hazard may include a situation that increases the likelihood of a fire or may impede escape in the event a fire occurs. Fire safety is often a component of building safety. Those who inspect buildings for violations of the Fire Code and go into schools to educate children on fire safety topics are fire department members known as ''Fire Prevention Officers''. The Chief Fire Prevention Officer or Chief of Fire Prevention will normally tr ...
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Globally Harmonized System Of Classification And Labeling Of Chemicals
The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms, and harmonized safety data sheets which provide users of dangerous goods with a host of information. The system acts as a complement to the UN Numbered system of regulated hazardous material transport. Implementation is managed through the UN Secretariat. Although adoption has taken time, as of 2017, the system has been enacted to significant extents in most major countries of the world. This includes the European Union, which has implemented the United Nations' GHS into EU law as the CLP Regulation, and United States Occupational Safety and Health Administration standards. History Before the Gl ...
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Fire
Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. At a certain point in the combustion reaction, called the ignition point, flames are produced. The '' flame'' is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different. Fire in its most common form can result in conflagration, which has the potential to cause physical damage through burning. Fire is an important process that affects ecological systems around the globe. The positive effects of fire include stimulating growth and maintaining various ecological systems. Its negative effects include hazard to life and property, atmospheric pollution, and water contamination. ...
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Flame Retardant
The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source and are intended to prevent or slow the further development of ignition by a variety of different physical and chemical methods. They may be added as a copolymer during the polymerisation process, or later added to the polymer at a moulding or extrusion process or (particularly for textiles) applied as a topical finish. Mineral flame retardants are typically additive while organohalogen and organophosphorus compounds can be either reactive or additive. Classes Both Reactive and Additive Flame retardants types, can be further separated into four distinct classes: * Minerals such as aluminium hydroxide (ATH), magnesium hydroxide (MDH), huntite and hydromagnesite, various hydrates, red phosphorus, and boron compounds, mostly borates. * Orga ...
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Polyurethane
Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from a wide range of starting materials. This chemical variety produces polyurethanes with different chemical structures leading to many different applications. These include rigid and flexible foams, varnishes and coatings, adhesives, electrical potting compounds, and fibers such as spandex and PUL. Foams are the largest application accounting for 67% of all polyurethane produced in 2016. A polyurethane is typically produced by reacting an isocyanate with a polyol. Since a polyurethane contains two types of monomers, which polymerize one after the other, they are classed as alternating copolymers. Both the isocyanates and polyols used to make a polyurethane contain two or more functional groups per molecule. Global production in 2019 wa ...
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Flammable Liquid
A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations. The Occupational Safety and Health Administration (OSHA) of the United States Department of Labor defines a liquid as flammable if it has a flash point at or below 199.4 °F (93 °C). Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 100 °F (37.8 °C). Those with flash points above 100 °F and below 200 °F (93.3 °C) were classified as combustible liquids. Studies show that the actual measure of a liquid's flammability, its flash point, is dependent on altitude. Categorization Both OSHA and GHS further divide flammable liquids into 4 categories ...
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Fire Protection
Fire protection is the study and practice of mitigating the unwanted effects of potentially destructive fires. It involves the study of the behaviour, compartmentalisation, suppression and investigation of fire and its related emergencies, as well as the research and development, production, testing and application of mitigating systems. In structures, be they land-based, offshore or even ships, the owners and operators are responsible to maintain their facilities in accordance with a design-basis that is rooted in laws, including the local building code and fire code, which are enforced by the authority having jurisdiction. Buildings must be constructed in accordance with the version of the building code that is in effect when an application for a building permit is made. Building inspectors check on compliance of a building under construction with the building code. Once construction is complete, a building must be maintained in accordance with the current fire code, which is ...
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HAZMAT Class 4 Flammable Solids
Flammable solids are any materials in the solid phase of matter that can readily undergo combustion in the presence of a source of ignition under standard circumstances, i.e. without: *Artificially changing variables such as pressure or density; or *Adding accelerants. Divisions Division 4.1: Flammable Solid Flammable solids are any of the following four types of materials: #Desensitized Explosives: explosives that, when dry, are Explosives of Class 1 other than those of compatibility group A, which are wetted with sufficient water, alcohol, or plasticizer to suppress explosive properties; and are specifically authorized by name either in the 49CFR 172.101 Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. #Self-Reactive Materials: materials that are thermally unstable and that can undergo a strongly exothermic decomposition even without participation of oxygen (air). Certain exclusions to this group do ap ...
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