Ferroelectric Materials
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Ferroelectric Materials
In physics and materials science, ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the additional property that their natural electrical polarization is reversible. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in Rochelle salt by American physicist Joseph Valasek.See and Thus, the prefix ''ferro'', meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron. Materials that are both ferroelectric ''and'' ferromagnetic are known as multiferroics. Polarization When most materials are electrically polarized, the polarization induced, ''P'', is almost exactly proportional to the applied exte ...
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Physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." It is one of the most fundamental scientific disciplines. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physics. (...) You will come to see physics as a towering achievement of ...
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Permittivity
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter (epsilon), is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor. In the simplest case, the electric displacement field resulting from an applied electric field E is \mathbf = \varepsilon\ \mathbf ~. More generally, the permittivity is a thermodynamic State function, function of state. It can depend on the Dispersion (optics), frequency, Nonlinear optics, magnitude, and Anisotropy, direction of the applied field. The International System of Units, SI unit for permittivity is farad per meter (F/m). The permittivity is often represented by the relative permittivity which is ...
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Sabatier Principle
In chemistry, the Sabatier principle is a qualitative concept in heterogeneous catalysis named after the French chemist Paul Sabatier. It states that the interactions between the catalyst and the reactants should be "just right"; that is, neither too strong nor too weak. If the interaction is too weak, the molecule will fail to bind to the catalyst and no reaction will take place. On the other hand, if the interaction is too strong, the product fails to dissociate. The principle can be shown graphically by plotting the reaction rate against a property such as the heat of adsorption of the reactant by the catalyst. Such plots pass through a maximum, looking roughly like a triangle or an inverted parabola, and are called volcano plots because of their shape. Analogous three-dimensional plots can also be built against two different properties, such as the heats of adsorption of the two reactants for a two-component reaction. In that case the plot is generally shown as a contour p ...
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Catalysis
Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst. The rate increase occurs because the catalyst allows the reaction to occur by an alternative mechanism which may be much faster than the noncatalyzed mechanism. However the noncatalyzed mechanism does remain possible, so that the total rate (catalyzed plus noncatalyzed) can only increase in the presence of the catalyst and never decrease. Catalysis may be classified as either homogeneous, whose components are dispersed in the same phase (usual ...
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Ferroelectric Tunnel Junction
A Ferroelectric tunnel junction (FTJ) is a form of tunnel junction including a ferroelectric dielectric material sandwiched between two electrically conducting materials. Electrons do not directly pass through the junction, and instead they pass the barrier via quantum tunnelling. The structure is similar to a ferroelectric capacitor, but the ferroelectric layer is fabricated thin enough to enable significant tunneling current. The magnitude of the tunneling current is switched by the ferroelectric polarization and is governed by the tunneling electroresistance (TER). There exists two conditions that must be met in order to manufacture a reliable FTJ: the FE-layer must be at maximum 3 nm in order to allow the electron tunneling (see section tunneling), and the interfaces on both sides need to be energetically asymmetrical in order to obtain two separate potential barrier heights. Description Ferroelectric tunnel junctions are being developed as a memristive component for ...
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Pyroelectricity
Pyroelectricity (from Greek: ''pyr'' (πυρ), "fire" and electricity) is a property of certain crystals which are naturally electrically polarized and as a result contain large electric fields. Pyroelectricity can be described as the ability of certain materials to generate a temporary voltage when they are heated or cooled. The change in temperature modifies the positions of the atoms slightly within the crystal structure, so that the polarization of the material changes. This polarization change gives rise to a voltage across the crystal. If the temperature stays constant at its new value, the pyroelectric voltage gradually disappears due to leakage current. The leakage can be due to electrons moving through the crystal, ions moving through the air, or current leaking through a voltmeter attached across the crystal. Explanation Pyroelectric charge in minerals develops on the opposite faces of asymmetric crystals. The direction in which the propagation of the charge tends is ...
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Piezoelectricity
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no inversion symmetry. The piezoelectric effect is a reversible process: materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an applied electric field. For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their static structure is deformed by about 0.1% of the original dimension. Conversely, those same crystals will change about 0.1% of their static dimension when an external electric field is applied. The inverse piezoelectric effect is used in the pro ...
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RFID
Radio-frequency identification (RFID) uses electromagnetic fields to automatically identify and track tags attached to objects. An RFID system consists of a tiny radio transponder called a tag, a radio receiver, and a transmitter. When triggered by an electromagnetic interrogation pulse from a nearby RFID reader device, the tag transmits digital data, usually an identifying inventory number, back to the reader. This number can be used to track inventory goods. Passive tags are powered by energy from the RFID reader's interrogating radio waves. Active tags are powered by a battery and thus can be read at a greater range from the RFID reader, up to hundreds of meters. Unlike a barcode, the tag does not need to be within the line of sight of the reader, so it may be embedded in the tracked object. RFID is one method of automatic identification and data capture (AIDC). RFID tags are used in many industries. For example, an RFID tag attached to an automobile during product ...
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Ferroelectric RAM
Ferroelectric RAM (FeRAM, F-RAM or FRAM) is a random-access memory similar in construction to DRAM but using a ferroelectric layer instead of a dielectric layer to achieve non-volatility. FeRAM is one of a growing number of alternative non-volatile random-access memory technologies that offer the same functionality as flash memory. An FeRAM chip contains a thin film of ferroelectric material, often lead zirconate titanate, commonly referred to as PZT. The atoms in the PZT layer change polarity in an electric field, thereby producing a power-efficient binary switch. However, the most important aspect of the PZT is that it is not affected by power disruption or magnetic interference, making FeRAM a reliable nonvolatile memory. FeRAM's advantages over Flash include: lower power usage, faster write speeds and a much greater maximum read/write endurance (about 1010 to 1015 cycles). FeRAMs have data retention times of more than 10 years at +85 °C (up to many decades at lower ...
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Ferroelectric Capacitor
Ferroelectric capacitor is a capacitor based on a ferroelectric material. In contrast, traditional capacitors are based on dielectric materials. Ferroelectric devices are used in digital electronics as part of ferroelectric RAM, or in analog electronics as tunable capacitors (varactors). In memory applications, the stored value of a ferroelectric capacitor is read by applying an electric field An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri .... The amount of charge needed to flip the memory cell to the opposite state is measured and the previous state of the cell is revealed. This means that the read operation destroys the memory cell state, and has to be followed by a corresponding write operation, in order to write the bit back. This makes it similar to (now obsolete) ferrite ...
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Curie Temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism is lost at a critical temperature. The force of magnetism is determined by the magnetic moment, a dipole moment within an atom that originates from the angular momentum and spin of electrons. Materials have different structures of intrinsic magnetic moments that depend on temperature; the Curie temperature is the critical point at which a material's intrinsic magnetic moments change direction. Permanent magnetism is caused by the alignment of magnetic moments, and induced magnetism is created when disordered magnetic moments are forced to align in an applied magnetic field. For example, the ordered magnetic moments (ferromagnetic, Figure 1) change and become disordered ( ...
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Magnetization
In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Accordingly, physicists and engineers usually define magnetization as the quantity of magnetic moment per unit volume. It is represented by a pseudovector M. Magnetization can be compared to Polarization density, electric polarization, which is the measure of the corresponding response of a material to an electric field in electrostatics. Magnetization also describes how a material responds to an applied magnetic field as well as the way the material changes the magnetic field, and can be used to calculate the forces that result from those interactions. The origin of the magnetic moments responsible for magnetization can be either microscopic electric currents resulting from the motion of electrons in atoms, or the Spin (physics), spin of the electrons or the nuclei. Net magnetization results from the response of a ...
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