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Cotton Effect
The Cotton effect in physics, is the characteristic change in optical rotatory dispersion and/or circular dichroism in the vicinity of an absorption band of a substance. In a wavelength region where the light is absorbed, the absolute magnitude of the optical rotation at first varies rapidly with wavelength, crosses zero at absorption maxima and then again varies rapidly with wavelength but in the opposite direction. This phenomenon was discovered in 1895 by the French physicist Aimé Cotton (1869–1951). The Cotton effect is called ''positive'' if the optical rotation first increases as the wavelength decreases (as first observed by Cotton), and ''negative'' if the rotation first decreases. A protein structure such as a beta sheet The beta sheet (β-sheet, also β-pleated sheet) is a common motif of the regular protein secondary structure. Beta sheets consist of beta strands (β-strands) connected laterally by at least two or three backbone hydrogen bonds, forming a gene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." It is one of the most fundamental scientific disciplines. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physics. (...) You will come to see physics as a towering achievement of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Rotatory Dispersion
In optics, optical rotatory dispersion is the variation of the specific rotation of a medium with respect to the wavelength of light. Usually described by German physicist Paul Drude's empirical relation: alpha\lambda^T=\sum_^\infty\frac where alpha\lambda^T is the specific rotation at temperature T and wavelength \lambda, and A_n and \lambda_n are constants that depend on the properties of the medium. Optical rotatory dispersion has applications in organic chemistry regarding determining the structure of organic compounds. Principles of operation When white light passes through a polarizer, the extent of rotation of light depends on its wavelength. Short wavelengths are rotated more than longer wavelengths, per unit of distance. Because the wavelength of light determines its color, the variation of color with distance through the tube is observed. This dependence of specific rotation on wavelength is called optical rotatory dispersion. In all materials the rotation va ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Circular Dichroism
Circular dichroism (CD) is dichroism involving circular polarization, circularly polarized light, i.e., the differential Absorption (electromagnetic radiation), absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum of light, spin angular momentum states for a photon, and so circular dichroism is also referred to as dichroism for spin angular momentum. This phenomenon was discovered by Jean-Baptiste Biot, Augustin Fresnel, and Aimé Cotton in the first half of the 19th century. Circular dichroism and optical rotation, circular birefringence are manifestations of optical activity. It is exhibited in the absorption (electromagnetic radiation), absorption bands of optical activity, optically active chirality (chemistry), chiral molecules. CD spectroscopy has a wide range of applications in many different fields. Most notably, Ultraviolet, far-UV CD is used to investigate the second ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absorption Band
In spectroscopy, an absorption band is a range of wavelengths, frequency, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance. According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific Quantum state, states. When such quantum, quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the radiation changes the state of the atom or molecule from an Ground state, initial state to a Excited state, final state. Overview When electromagnetic radiation is absorbed by an atom or molecule, the energy of the radiation changes the state of the atom or molecule from an Ground state, initial state to a Excited state, final state. The number of states in a specific energy range is discrete for gaseous or diluted systems, with discrete energy levels. Condensed matter physics, Condensed systems, lik ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Rotation
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes (such as quartz) or metamaterials. When looking at the source of light, the rotation of the plane of polarization may be either to the right (dextrorotatory ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aimé Cotton
Aimé Auguste Cotton (9 October 1869 – 16 April 1951) was a French physicist known for his studies of the interaction of light with chiral molecules. In the absorption bands of these molecules, he discovered large values of optical rotatory dispersion (ORD), or variation of optical rotation as a function of wavelength ( Cotton effect), as well as circular dichroism or differences of absorption between left and right circularly polarized light. Biography Early years Aimé Cotton was born in Bourg-en-Bresse, Ain on 9 October 1869. His grandfather was director of the École normale (teachers' college) of Bourg, and his father, Eugène Cotton, was a mathematics professor at the college of Bourg, the institution where physicist André-Marie Ampère began his career. Aimé's brother Émile Cotton was a mathematician and academician. Aimé Cotton attended a lycée (high school) in Bourg and then the special mathematics program at the Lycée Blaise Pascal in Clermont-Ferra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beta Sheet
The beta sheet (β-sheet, also β-pleated sheet) is a common motif of the regular protein secondary structure. Beta sheets consist of beta strands (β-strands) connected laterally by at least two or three backbone hydrogen bonds, forming a generally twisted, pleated sheet. A β-strand is a stretch of polypeptide chain typically 3 to 10 amino acids long with backbone in an extended conformation. The supramolecular association of β-sheets has been implicated in the formation of the fibrils and protein aggregates observed in amyloidosis, Alzheimer's disease and other proteinopathies. History The first β-sheet structure was proposed by William Astbury in the 1930s. He proposed the idea of hydrogen bonding between the peptide bonds of parallel or antiparallel extended β-strands. However, Astbury did not have the necessary data on the bond geometry of the amino acids in order to build accurate models, especially since he did not then know that the peptide bond was planar. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polarization (waves)
, or , is a property of transverse waves which specifies the geometrical orientation of the oscillations. In a transverse wave, the direction of the oscillation is perpendicular to the direction of motion of the wave. One example of a polarized transverse wave is vibrations traveling along a taut string, for example, in a musical instrument like a guitar string. Depending on how the string is plucked, the vibrations can be in a vertical direction, horizontal direction, or at any angle perpendicular to the string. In contrast, in longitudinal waves, such as sound waves in a liquid or gas, the displacement of the particles in the oscillation is always in the direction of propagation, so these waves do not exhibit polarization. Transverse waves that exhibit polarization include electromagnetic waves such as light and radio waves, gravitational waves, and transverse sound waves ( shear waves) in solids. An electromagnetic wave such as light consists of a coupled oscillating el ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
