Anode-free Battery
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Anode-free Battery
An anode-free battery (AFB) is one that is manufactured without an anode. Instead, it creates a metal anode the first time it is charged. The anode is formed from charge carriers supplied by the cathode. As such, before charging, the battery consists of a cathode, current collectors, separator and electrolyte. Background Conventional batteries use an anode made of graphite. However, the graphite consumes space, adds weight, adds to materials costs, and increases manufacturing complexity. As of 2023, the most practical designs that support lithium metal batteries are anode-free. Design Anode-free batteries typically require a solid-state electrolyte made of a ceramic or polymer. This is to ensure that over many charge/discharge cycles, dendrites that may form on the anode-side current collector do not cross the electrolyte and short circuit the battery. Some solid-state designs use conventional graphite anodes. The charge carriers electroplate lithium onto the anode current col ...
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Charge Carrier
In solid state physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. In a conducting medium, an electric field can exert force on these free particles, causing a net motion of the particles through the medium; this is what constitutes an electric current. The electron and the proton are the elementary charge carriers, each carrying one elementary charge (''e''), of the same magnitude and opposite sign. In conductors In conducting mediums, particles serve to carry charge. In many metals, the charge carriers are electrons. One or two of the valence electrons from each atom are able to move about freely within the crystal structure of the metal. The free electrons are referred to as conduction electrons, and the cloud of free electrons is called a Fermi gas. Many metals have electron and hole bands. In ...
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Lithium Sulfide
Lithium sulfide is the inorganic compound with the formula Li2 S. It crystallizes in the antifluorite motif, described as the salt (Li+)2S2−. It forms a solid yellow-white deliquescent powder. In air, it easily hydrolyses to release foul smelling hydrogen sulfide gas. Preparation Lithium sulfide is prepared by treating lithium with sulfur. This reaction is conveniently conducted in anhydrous ammonia. :2 Li + S → Li2S The THF-soluble triethylborane Triethylborane (TEB), also called triethylboron, is an organoborane (a compound with a B–C bond). It is a colorless pyrophoric liquid. Its chemical formula is or , abbreviated . It is soluble in organic solvents tetrahydrofuran and hexane. ... adduct of lithium sulfide can be generated using superhydride. Reactions and applications Lithium sulfide has been considered for use in lithium–sulfur batteries. References External links Lithium Sulfide {{Sulfides Lithium salts Sulfides Fluorite crystal structure< ...
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MXenes
In materials science, MXenes (pronounced "max-enes") are a class of two-dimensional inorganic compounds along with MBorenes, that consist of atomically thin layers of transition metal carbides, nitrides, or carbonitrides. MXenes accept a variety of hydrophilic terminations. The first MXene was reported in 2011 at Drexel University's College of Engineering, and were named by combining the prefix "MAX" or "MX" (for MAX phases), with "ene" by analogy to graphene. Structure As-synthesized MXenes prepared via HF etching have an accordion-like morphology, which can be referred to as multi-layer MXene (ML-MXene), or few-layer MXene (FL-MXene) given fewer than five layers. Because the surfaces of MXenes can be terminated by functional groups, the naming convention Mn+1XnTx can be used, where T is a functional group (e.g. O, F, OH, Cl). Mono transition MXenes adopt three structures with one metal on the M site, as inherited from the parent MAX phases: M2C, M3C2, and M4C3. They are ...
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United States Department Of Energy
The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and energy production, the research and development of nuclear power, the military's nuclear weapons program, nuclear reactor production for the United States Navy, energy-related research, and energy conservation. The DOE was created in 1977 in the aftermath of the 1973 oil crisis. It sponsors more physical science research than any other U.S. federal agency, the majority of which is conducted through its system of National Laboratories. The DOE also directs research in genomics, with the Human Genome Project originating from a DOE initiative. The department is headed by the secretary of energy, who reports directly to the president of the United States and is a member of the Cabinet. The current secretary of energy is Chris Wright, who has served in the position since February 2025. The department's headquarters are in sou ...
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Advanced Research Projects Agency–Energy
ARPA-E, or Advanced Research Projects Agency–Energy is an agency within the United States Department of Energy tasked with funding the research and development of advanced energy technologies. The goal of the agency is to improve U.S. economic prosperity, national security, and environmental well being. ARPA-E typically funds short-term research projects with the potential for a transformative impact. It is inspired by the Defense Advanced Research Projects Agency (DARPA). The program directors at ARPA-E serve limited terms, in an effort to reduce bureaucracy and bias. the director is Evelyn Wang. History and mission Legislative history ARPA-E was initially conceived by a report by the National Academies entitled ''Rising Above the Gathering Storm: Energizing and Employing America for a Brighter Economic Future''. The report described a need for the US to stimulate innovation and develop clean, affordable, and reliable energy. ARPA-E was officially created by the America C ...
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Pacific Northwest National Laboratory
Pacific Northwest National Laboratory (PNNL) is one of the United States Department of Energy national laboratories, managed by the Department of Energy's (DOE) Office of Science. The main campus of the laboratory is in Richland, Washington, with additional research facilities around the country. Originally named the Pacific Northwest Laboratory, PNL was established in 1965 when research and development at the Hanford Site was separated from other Hanford operations. In 1995, the laboratory was renamed the Pacific Northwest National Laboratory (PNNL). Research facilities The Environmental Molecular Sciences Laboratory (EMSL) is a U.S. Department of Energy national scientific user facility. EMSL provides researchers around the world with integrated capabilities in oxide and mineral interface chemistry, high-performance computing and computational chemistry software, mass spectrometry, high-field magnetic resonance, and subsurface flow and transport research. The Biopr ...
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Coulombic Efficiency
In electrochemistry, Faraday efficiency (also called faradaic efficiency, faradaic yield, coulombic efficiency, or current efficiency) describes the efficiency with which charge (electrons) is transferred in a system facilitating an electrochemical reaction. The word "Faraday" in this term has two interrelated aspects: first, the historic unit for charge is the faraday (F), but has since been replaced by the coulomb (C); and secondly, the related Faraday's constant () correlates charge with moles of matter and electrons (amount of substance). This phenomenon was originally understood through Michael Faraday's work and expressed in his laws of electrolysis. Sources of faradaic loss Faradaic losses are experienced by both electrolytic and galvanic cells when electrons or ions participate in unwanted side reactions. These losses appear as heat and/or chemical byproducts. An example can be found in the oxidation of water to oxygen at the positive electrode in electrolysis. Hydr ...
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Solid-state Battery
A solid-state battery (SSB) is an electrical battery that uses a solid electrolyte (''solectro'') to conduct ions between the electrodes, instead of the liquid or gel polymer electrolytes found in conventional batteries. Solid-state batteries theoretically offer much higher energy density than the typical lithium-ion or lithium polymer batteries. While solid electrolytes were first discovered in the 19th century, several problems prevented widespread application. Developments in the late 20th and early 21st century generated renewed interest in the technology, especially in the context of electric vehicles. Solid-state batteries can use metallic lithium for the anode and oxides or sulfides for the cathode, increasing energy density. The solid electrolyte acts as an ideal separator that allows only lithium ions to pass through. For that reason, solid-state batteries can potentially solve many problems of currently used liquid electrolyte Li-ion batteries, such as flammabil ...
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Energy Density
In physics, energy density is the quotient between the amount of energy stored in a given system or contained in a given region of space and the volume of the system or region considered. Often only the ''useful'' or extractable energy is measured. It is sometimes confused with stored energy per unit mass, which is called ''specific energy'' or . There are different types of energy stored, corresponding to a particular type of reaction. In order of the typical magnitude of the energy stored, examples of reactions are: Nuclear power, nuclear, Chemical energy, chemical (including Electrochemistry, electrochemical), electrical, pressure, Deformation (engineering), material deformation or in Electromagnetic field, electromagnetic fields. Nuclear reactions take place in stars and nuclear power plants, both of which derive energy from the binding energy of nuclei. Chemical reactions are used by organisms to derive energy from food and by automobiles from the combustion of gasoline. Liqu ...
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QuantumScape
QuantumScape is an American company that develops solid-state rechargeable lithium metal batteries for electric cars. The company is headquartered in San Jose, California and employs around 850 people. Investors include Bill Gates and Volkswagen. History QuantumScape was founded in 2010 by Jagdeep Singh, Tim Holme and Professor Fritz Prinz of Stanford University. In 2012, QuantumScape began working with German automaker Volkswagen. In 2018, Volkswagen invested $100 million in the company, becoming the largest shareholder. In the same year, Volkswagen and QuantumScape announced the establishment of a joint production project to prepare for mass production of solid-state batteries. In June 2020, Volkswagen invested an additional $200 million. In 2020, QuantumScape merged with the special-purpose acquisition company Kensington Capital Acquisition. As a result of the merger, QuantumScape received $1 billion in financing, from investors including Volkswagen and the Qatar ...
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Reactive Oxygen Species
In chemistry and biology, reactive oxygen species (ROS) are highly Reactivity (chemistry), reactive chemicals formed from diatomic oxygen (), water, and hydrogen peroxide. Some prominent ROS are hydroperoxide (H2O2), superoxide (O2−), hydroxyl radical (OH.), and singlet oxygen(1O2). ROS are pervasive because they are readily produced from O2, which is abundant. ROS are important in many ways, both beneficial and otherwise. ROS function as signals, that turn on and off biological functions. They are intermediates in the redox behavior of O2, which is central to fuel cells. ROS are central to the photodegradation of organic pollutants in the atmosphere. Most often however, ROS are discussed in a biological context, ranging from their effects on aging and their role in causing dangerous genetic mutations. Inventory of ROS ROS are not uniformly defined. All sources include superoxide, singlet oxygen, and hydroxyl radical. Hydrogen peroxide is not nearly as reactive as these s ...
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Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional current describes the direction in which positive charges move. Electrons, which are the carriers of current in most electrical systems, have a negative electrical charge, so the movement of electrons is ''opposite'' to that of the conventional current flow: this means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity ...
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